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dc.contributor.authorSun, Tai
dc.contributor.authorWang, Hui
dc.contributor.authorZhang, Qingan
dc.contributor.authorSun, Dalin
dc.contributor.authorYao, Xiangdong
dc.contributor.authorZhu, Min
dc.date.accessioned2017-05-03T15:45:12Z
dc.date.available2017-05-03T15:45:12Z
dc.date.issued2011
dc.date.modified2012-04-09T23:17:24Z
dc.identifier.issn0959-9428
dc.identifier.doi10.1039/C1JM10354G
dc.identifier.urihttp://hdl.handle.net/10072/44318
dc.description.abstractTo improve the hydrogen storage performance, Mg(3)La alloy and TiCl(3) is ball milled simultaneously with LiBH(4) to yield a designed composition. It has been revealed that there is a synergistic effect of Mg(3)La alloy and TiCl(3) on the dehydrogenation of LiBH(4), which improves the dehydrogenation performance when compared to adding either hydrogenated Mg(3)La or TiCl(3) alone. 4.3 wt% of H(2) can be released within 10 min at 400 degrees C in the LiBH(4) + Mg(3)La + TiCl(3) system. The dehydrogenation activation energy of this system is 52.6 kJ mol(-1), which is much lower than that of pristine LiBH(4). In addition, the LiBH(4) + Mg(3)La + TiCl(3) system preserves fast dehydrogenation kinetics and stable hydrogen storage capacity in the re-/dehydrogenation cycles.
dc.description.peerreviewedYes
dc.description.publicationstatusYes
dc.languageEnglish
dc.language.isoeng
dc.publisherRoyal Society of Chemistry
dc.publisher.placeUnited Kingdom
dc.relation.ispartofstudentpublicationN
dc.relation.ispartofpagefrom9179
dc.relation.ispartofpageto9184
dc.relation.ispartofissue25
dc.relation.ispartofjournalJournal of Materials Chemistry
dc.relation.ispartofvolume21
dc.rights.retentionY
dc.subject.fieldofresearchSynthesis of Materials
dc.subject.fieldofresearchChemical Sciences
dc.subject.fieldofresearchEngineering
dc.subject.fieldofresearchcode030306
dc.subject.fieldofresearchcode03
dc.subject.fieldofresearchcode09
dc.titleSynergetic effects of hydrogenated Mg3La and TiCl3 on the dehydrogenation of LiBH4
dc.typeJournal article
dc.type.descriptionC1 - Articles
dc.type.codeC - Journal Articles
gro.date.issued2011
gro.hasfulltextNo Full Text
gro.griffith.authorYao, Xiangdong


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