A novel low density metal-organic framework with pcu topology by dendritic ligand
Author(s)
Jia, Jiangtao
Sun, Fuxing
Fang, Qianrong
Liang, Xiaoqiang
Cai, Kun
Bian, Zheng
Zhao, Huijun
Gao, Lianxun
Zhu, Guangshan
Griffith University Author(s)
Year published
2011
Metadata
Show full item recordAbstract
A novel low density two-fold interpenetrated MOF-5 analogue with pcu topology, JUC-100, was designed and prepared successfully. It can be regarded as MOF-5 in which half of the Zn4O(CO2)6 units are replaced by organic 1,3,5-triphenylbenzene segments. JUC-100 exhibits H2 uptake ability comparable to interpenetrated MOF-5, but relatively low initial isosteric heat of adsorption.A novel low density two-fold interpenetrated MOF-5 analogue with pcu topology, JUC-100, was designed and prepared successfully. It can be regarded as MOF-5 in which half of the Zn4O(CO2)6 units are replaced by organic 1,3,5-triphenylbenzene segments. JUC-100 exhibits H2 uptake ability comparable to interpenetrated MOF-5, but relatively low initial isosteric heat of adsorption.
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Journal Title
Chemical Communications
Volume
47
Issue
32
Subject
Chemical sciences
Chemical engineering not elsewhere classified