An efficient synthesis of selectively functionalized D-rhamnose derivatives

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Author(s)
Zunk, Matthew
Kiefel, Milton J
Year published
2011
Metadata
Show full item recordAbstract
D-Rhamnose is an important component of bacterial lipopolysaccharides. This paper describes a short and highly efficient synthesis of D-rhamnose from D-mannose. The synthesis of selectively C-4 modified Drhamnosides and 6-deoxy-D-talosides as potential building blocks for complex oligosaccharide synthesis is also discussed.D-Rhamnose is an important component of bacterial lipopolysaccharides. This paper describes a short and highly efficient synthesis of D-rhamnose from D-mannose. The synthesis of selectively C-4 modified Drhamnosides and 6-deoxy-D-talosides as potential building blocks for complex oligosaccharide synthesis is also discussed.
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Journal Title
Tetrahedron Letters
Volume
52
Issue
12
Copyright Statement
© 2011 Elsevier. This is the author-manuscript version of this paper. Reproduced in accordance with the copyright policy of the publisher. Please refer to the journal's website for access to the definitive, published version.
Subject
Organic Chemistry not elsewhere classified
Medicinal and Biomolecular Chemistry
Organic Chemistry