An efficient synthesis of selectively functionalized D-rhamnose derivatives

Zunk, Matthew; Kiefel, Milton J

doi:10.1016/j.tetlet.2011.01.064

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Author(s)

Zunk, Matthew

Kiefel, Milton J

Griffith University Author(s)

Kiefel, Milton

Zunk, Matthew S.

Year published

2011

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Abstract

D-Rhamnose is an important component of bacterial lipopolysaccharides. This paper describes a short and highly efficient synthesis of D-rhamnose from D-mannose. The synthesis of selectively C-4 modified Drhamnosides and 6-deoxy-D-talosides as potential building blocks for complex oligosaccharide synthesis is also discussed.D-Rhamnose is an important component of bacterial lipopolysaccharides. This paper describes a short and highly efficient synthesis of D-rhamnose from D-mannose. The synthesis of selectively C-4 modified Drhamnosides and 6-deoxy-D-talosides as potential building blocks for complex oligosaccharide synthesis is also discussed.
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Journal Title

Tetrahedron Letters

Volume

Issue

DOI

https://doi.org/10.1016/j.tetlet.2011.01.064

Copyright Statement

© 2011 Elsevier. This is the author-manuscript version of this paper. Reproduced in accordance with the copyright policy of the publisher. Please refer to the journal's website for access to the definitive, published version.

Subject

Organic Chemistry not elsewhere classified

Organic Chemistry

Medicinal and Biomolecular Chemistry

Publication URI

http://hdl.handle.net/10072/44399

Collection

Journal articles