The synthesis, structure and photoluminescence property of a novel 3D supramolecular compound based on mixed ligands of 8-hydroxyquinoline-5-sulfonate and ethylenediamine
MetadataShow full item record
A new organic-inorganic hybrid coordination compound ZnQS(en)粈2O (1) in which two different organic ligands, ethylenediamine (en) and 8-hydroxyquinoline-5-sulfonic acid (H2QS) coordinate with zinc ions, has been synthesized via the evaporation method and characterized by single crystal X-ray diffraction analysis, IR spectroscopy and thermogravimetric analysis (TGA). The structure solution showed that compound 1 displays a three-dimensional supramolecular network by synergic linkage of hydrogen and coordinated bonds. Moreover, compound 1 exhibits intense photoluminescence at 513 nm excited at 396 nm in the solid state at room temperature.
Journal of the Serbian Chemical Society
Copyright remains with the authors 2011. This is an Open Access article distributed under the terms of the Creative Commons Attribution 3.0 License (http://creativecommons.org/licenses/by/3.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
Inorganic Chemistry not elsewhere classified