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  • The synthesis, structure and photoluminescence property of a novel 3D supramolecular compound based on mixed ligands of 8-hydroxyquinoline-5-sulfonate and ethylenediamine

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    Author(s)
    Wang, Ying
    Zhuang, Changfu
    Wu, Chunhua
    Zhang, Jiayan
    Wang, Li
    Xin, Minghong
    Zhu, Guangshan
    Xu, Jianing
    Griffith University Author(s)
    Zhu, Guangshan
    Year published
    2011
    Metadata
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    Abstract
    A new organic-inorganic hybrid coordination compound ZnQS(en)粈2O (1) in which two different organic ligands, ethylenediamine (en) and 8-hydroxyquinoline-5-sulfonic acid (H2QS) coordinate with zinc ions, has been synthesized via the evaporation method and characterized by single crystal X-ray diffraction analysis, IR spectroscopy and thermogravimetric analysis (TGA). The structure solution showed that compound 1 displays a three-dimensional supramolecular network by synergic linkage of hydrogen and coordinated bonds. Moreover, compound 1 exhibits intense photoluminescence at 513 nm excited at 396 nm in the solid state ...
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    A new organic-inorganic hybrid coordination compound ZnQS(en)粈2O (1) in which two different organic ligands, ethylenediamine (en) and 8-hydroxyquinoline-5-sulfonic acid (H2QS) coordinate with zinc ions, has been synthesized via the evaporation method and characterized by single crystal X-ray diffraction analysis, IR spectroscopy and thermogravimetric analysis (TGA). The structure solution showed that compound 1 displays a three-dimensional supramolecular network by synergic linkage of hydrogen and coordinated bonds. Moreover, compound 1 exhibits intense photoluminescence at 513 nm excited at 396 nm in the solid state at room temperature.
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    Journal Title
    Journal of the Serbian Chemical Society
    Volume
    76
    Issue
    11
    DOI
    https://doi.org/10.2298/JSC110129127W
    Copyright Statement
    © The Author(s) 2011. This is an Open Access article distributed under the terms of the Creative Commons Attribution 3.0 License (http://creativecommons.org/licenses/by/3.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
    Subject
    Inorganic Chemistry not elsewhere classified
    Chemical Sciences
    Publication URI
    http://hdl.handle.net/10072/44440
    Collection
    • Journal articles

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