The synthesis, structure and photoluminescence property of a novel 3D supramolecular compound based on mixed ligands of 8-hydroxyquinoline-5-sulfonate and ethylenediamine
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Author(s)
Wang, Ying
Zhuang, Changfu
Wu, Chunhua
Zhang, Jiayan
Wang, Li
Xin, Minghong
Zhu, Guangshan
Xu, Jianing
Griffith University Author(s)
Year published
2011
Metadata
Show full item recordAbstract
A new organic-inorganic hybrid coordination compound ZnQS(en)粈2O (1) in which two different organic ligands, ethylenediamine (en) and 8-hydroxyquinoline-5-sulfonic acid (H2QS) coordinate with zinc ions, has been synthesized via the evaporation method and characterized by single crystal X-ray diffraction analysis, IR spectroscopy and thermogravimetric analysis (TGA). The structure solution showed that compound 1 displays a three-dimensional supramolecular network by synergic linkage of hydrogen and coordinated bonds. Moreover, compound 1 exhibits intense photoluminescence at 513 nm excited at 396 nm in the solid state ...
View more >A new organic-inorganic hybrid coordination compound ZnQS(en)粈2O (1) in which two different organic ligands, ethylenediamine (en) and 8-hydroxyquinoline-5-sulfonic acid (H2QS) coordinate with zinc ions, has been synthesized via the evaporation method and characterized by single crystal X-ray diffraction analysis, IR spectroscopy and thermogravimetric analysis (TGA). The structure solution showed that compound 1 displays a three-dimensional supramolecular network by synergic linkage of hydrogen and coordinated bonds. Moreover, compound 1 exhibits intense photoluminescence at 513 nm excited at 396 nm in the solid state at room temperature.
View less >
View more >A new organic-inorganic hybrid coordination compound ZnQS(en)粈2O (1) in which two different organic ligands, ethylenediamine (en) and 8-hydroxyquinoline-5-sulfonic acid (H2QS) coordinate with zinc ions, has been synthesized via the evaporation method and characterized by single crystal X-ray diffraction analysis, IR spectroscopy and thermogravimetric analysis (TGA). The structure solution showed that compound 1 displays a three-dimensional supramolecular network by synergic linkage of hydrogen and coordinated bonds. Moreover, compound 1 exhibits intense photoluminescence at 513 nm excited at 396 nm in the solid state at room temperature.
View less >
Journal Title
Journal of the Serbian Chemical Society
Volume
76
Issue
11
Copyright Statement
© The Author(s) 2011. This is an Open Access article distributed under the terms of the Creative Commons Attribution 3.0 License (http://creativecommons.org/licenses/by/3.0/), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
Subject
Inorganic Chemistry not elsewhere classified
Chemical Sciences