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  • 溶剂效应对金属有机骨架化合物结构的影响

    Author(s)
    Guang-Shan, Zhu
    Huan-Yu, Zhao
    Zhao, Jin
    Fuxing, Sun
    Griffith University Author(s)
    Zhu, Guangshan
    Year published
    2011
    Metadata
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    Abstract
    Two novel compounds Cd(OBA)(bipy)?DMF (1) and Cd(OBA)(bipy) (2) (OBA = 4,4'-Oxybis(benzoic acid), bipy = 4,4'-bipyridine) were synthesized under hydrothermal (solvothermal) by using DMF and water as solvent respectively. X-ray diffraction analyses reveal that both the compounds are in the monoclinic and C2/c space group Compound 1 exhibits a two-dimension framework and compound 2 is a three-dimension framework.Two novel compounds Cd(OBA)(bipy)?DMF (1) and Cd(OBA)(bipy) (2) (OBA = 4,4'-Oxybis(benzoic acid), bipy = 4,4'-bipyridine) were synthesized under hydrothermal (solvothermal) by using DMF and water as solvent respectively. X-ray diffraction analyses reveal that both the compounds are in the monoclinic and C2/c space group Compound 1 exhibits a two-dimension framework and compound 2 is a three-dimension framework.
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    Journal Title
    Chemical Journal of Chinese Universities
    Volume
    32
    Issue
    3
    Publisher URI
    http://www.cjcu.jlu.edu.cn/EN/abstract/abstract13470.shtml
    Subject
    Inorganic Chemistry not elsewhere classified
    Chemical Sciences
    Publication URI
    http://hdl.handle.net/10072/44946
    Collection
    • Journal articles

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