溶剂效应对金属有机骨架化合物结构的影响

Abstract

Two novel compounds Cd(OBA)(bipy)?DMF (1) and Cd(OBA)(bipy) (2) (OBA = 4,4'-Oxybis(benzoic acid), bipy = 4,4'-bipyridine) were synthesized under hydrothermal (solvothermal) by using DMF and water as solvent respectively. X-ray diffraction analyses reveal that both the compounds are in the monoclinic and C2/c space group Compound 1 exhibits a two-dimension framework and compound 2 is a three-dimension framework.