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  • Bis[2-(diphenylphosphanyl-kP)-benzaldehyde]iodidogold(I)

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    80238_1.pdf (546.4Kb)
    Author(s)
    Williams, ML
    Dunstan, SPC
    Healy, PC
    Tiekink, ERT
    Griffith University Author(s)
    Healy, Peter C.
    Williams, Michael L.
    Dunstan, Sam
    Year published
    2012
    Metadata
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    Abstract
    In the title compound, [AuI(C19H15OP)2], the complete mol­ecule is generated by the application of twofold symmetry. The AuI atom is in a trigonal-planar geometry within an IP2 donor set with the greatest distortion seen in the P-Au-P angle [128.49 (3) °]. Close intra­molecular Au...O inter­actions [3.172 (3) Å] are observed. No specific inter­molecular inter­actions are noted in the crystal packing.In the title compound, [AuI(C19H15OP)2], the complete mol­ecule is generated by the application of twofold symmetry. The AuI atom is in a trigonal-planar geometry within an IP2 donor set with the greatest distortion seen in the P-Au-P angle [128.49 (3) °]. Close intra­molecular Au...O inter­actions [3.172 (3) Å] are observed. No specific inter­molecular inter­actions are noted in the crystal packing.
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    Journal Title
    Acta Crystallographica. Section E: Structure Reports Online
    Volume
    E68
    Issue
    4
    DOI
    https://doi.org/10.1107/S1600536812011609
    Copyright Statement
    © The Author(s) 2012. For information about this journal please refer to the journal’s website. All articles published in Acta Crystallographica Section E are open access and distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. See http://creativecommons.org/licenses/by/2.0/uk/legalcode
    Subject
    Transition Metal Chemistry
    Structural Chemistry and Spectroscopy
    Chemical Sciences
    Publication URI
    http://hdl.handle.net/10072/47903
    Collection
    • Journal articles

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