Luminescence characteristics and X-ray crystal structure of [Cd(bipy)3][PF6]2 (bipy) = 2,2'-bipyridine)
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The photoluminescence characteristics of the [Cd(bipy)3][PF6]2 complex are reported. A moderately large quantum yield (f) of 1.07 נ10-2 is exhibited in acetonitrile solution at 298 K. Crystallography shows the dication to have a distorted octahedral geometry and the crystal structure to be stabilized by C[BOND]H緷p and C[BOND]H緷F interactions.
Applied Organometallic Chemistry