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dc.contributor.authorJepps, Owenen_US
dc.contributor.authorK. Bhatia, Sureshen_US
dc.contributor.authorBernhardt, Debraen_US
dc.date.accessioned2017-05-03T12:18:37Z
dc.date.available2017-05-03T12:18:37Z
dc.date.issued2005en_US
dc.date.modified2009-09-24T05:55:34Z
dc.identifier.issn07437463en_US
dc.identifier.doi10.1021/la047984gen_AU
dc.identifier.urihttp://hdl.handle.net/10072/4950
dc.description.abstractIt is a common approximation in the modeling of adsorption in microporous carbons to treat the pores as slit pores, whose walls are considered to consist of an infinite number of graphitic layers. In practice, such an approximation is appropriate as long as the number of graphitic layers in the wall is greater than three. However, it is understood that pore walls in microporous carbons commonly consist of three or fewer layers. As well as affecting the solid-fluid interaction within a pore, such narrow walls permit the interaction of fluid molecules through the wall, with consequences for the adsorption characteristics. We consider the effect that a distributed pore-wall thickness model can have on transport properties. At low density we find that the only significant deviation in the transport properties from the infinite pore-wall thickness model occurs in pores with single-layer walls. For a model of activated carbons with a distribution of pore widths and pore-wall thicknesses, the transport properties are generally insensitive to the effects of finite walls, in terms of both the solid-fluid interaction within a pore and fluid-fluid interaction through the pore walls.en_US
dc.description.peerreviewedYesen_US
dc.description.publicationstatusYesen_AU
dc.languageEnglishen_US
dc.language.isoen_AU
dc.publisherAmerican Chemical Societyen_US
dc.publisher.placeWashington, DCen_US
dc.publisher.urihttp://pubs.acs.org/journal/langd5en_AU
dc.relation.ispartofstudentpublicationNen_AU
dc.relation.ispartofpagefrom229en_US
dc.relation.ispartofpageto239en_US
dc.relation.ispartofjournalLangmuir: the ACS journal of surfaces and colloidsen_US
dc.relation.ispartofvolume21en_US
dc.rights.retentionYen_AU
dc.subject.fieldofresearchcode250103en_US
dc.titleEffects of the Juxtaposition of Carbonaceous slit pores on the overall transport behavior of adsorbed fluidsen_US
dc.typeJournal articleen_US
dc.type.descriptionC1 - Peer Reviewed (HERDC)en_US
dc.type.codeC - Journal Articlesen_US
gro.date.issued2005
gro.hasfulltextNo Full Text


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