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  • Synthesis and characterization of germanium-centered three-dimensional crystalline porous aromatic framework

    Author(s)
    Yuan, Ye
    Liu, Jia
    Ren, Hao
    Jing, Xiaofei
    Wang, Wei
    Ma, Heping
    Sun, Fuxing
    Zhao, Huijun
    Griffith University Author(s)
    Zhao, Huijun
    Year published
    2012
    Metadata
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    Abstract
    Tetra(4-dihydroxyborylphenyl)germanium as the tetrahedral units and 1,2,4,5-tetrahydroxybenzene as linkers were selected to form a crystalline porous aromatic framework, CPAF-13, with the planar five-membered BO2C2 ring in its structure by a dehydration reaction. The crystallinity of CPAF-13 was confirmed by x-ray diffraction analysis. The Ar sorption measurement on activated CPAF-13 results in a surface area of 417 m2/g, using Brunauer Emmett Teller model. CPAF-13 also shows a considerable adsorption capacity of H2.Tetra(4-dihydroxyborylphenyl)germanium as the tetrahedral units and 1,2,4,5-tetrahydroxybenzene as linkers were selected to form a crystalline porous aromatic framework, CPAF-13, with the planar five-membered BO2C2 ring in its structure by a dehydration reaction. The crystallinity of CPAF-13 was confirmed by x-ray diffraction analysis. The Ar sorption measurement on activated CPAF-13 results in a surface area of 417 m2/g, using Brunauer Emmett Teller model. CPAF-13 also shows a considerable adsorption capacity of H2.
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    Journal Title
    Journal of Materials Research
    Volume
    27
    Issue
    10
    DOI
    https://doi.org/10.1557/jmr.2011.433
    Subject
    Condensed matter physics
    Inorganic green chemistry
    Materials engineering
    Mechanical engineering
    Publication URI
    http://hdl.handle.net/10072/49915
    Collection
    • Journal articles

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