Synthesis and characterization of germanium-centered three-dimensional crystalline porous aromatic framework
Author(s)
Yuan, Ye
Liu, Jia
Ren, Hao
Jing, Xiaofei
Wang, Wei
Ma, Heping
Sun, Fuxing
Zhao, Huijun
Griffith University Author(s)
Year published
2012
Metadata
Show full item recordAbstract
Tetra(4-dihydroxyborylphenyl)germanium as the tetrahedral units and 1,2,4,5-tetrahydroxybenzene as linkers were selected to form a crystalline porous aromatic framework, CPAF-13, with the planar five-membered BO2C2 ring in its structure by a dehydration reaction. The crystallinity of CPAF-13 was confirmed by x-ray diffraction analysis. The Ar sorption measurement on activated CPAF-13 results in a surface area of 417 m2/g, using Brunauer Emmett Teller model. CPAF-13 also shows a considerable adsorption capacity of H2.Tetra(4-dihydroxyborylphenyl)germanium as the tetrahedral units and 1,2,4,5-tetrahydroxybenzene as linkers were selected to form a crystalline porous aromatic framework, CPAF-13, with the planar five-membered BO2C2 ring in its structure by a dehydration reaction. The crystallinity of CPAF-13 was confirmed by x-ray diffraction analysis. The Ar sorption measurement on activated CPAF-13 results in a surface area of 417 m2/g, using Brunauer Emmett Teller model. CPAF-13 also shows a considerable adsorption capacity of H2.
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Journal Title
Journal of Materials Research
Volume
27
Issue
10
Subject
Condensed matter physics
Inorganic green chemistry
Materials engineering
Mechanical engineering