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  • Boron-Carbohydrate Interactions

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    PappinPUB25.pdf (601.4Kb)
    Author(s)
    Pappin, Brighid
    Kiefel, Milton J
    Houston, Todd A
    Griffith University Author(s)
    Kiefel, Milton
    Houston, Todd A.
    Pappin, Brighid B.
    Year published
    2012
    Metadata
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    Abstract
    Boron-polyol interactions are of fundamental importance to human health [1], plant growth [2] and quorum sensing among certain bacteria [3]. Such diversity is perhaps not surprising when one considers boron is one of the ten most abundant elements in sea water and carbohydrates make up the planet’s most abundant class of biomass. Several boronic acids matrices are commercially available for the purification of glycoproteins by affinity chromatography [4], and boronic acids are also useful carbohydrate protecting groups.[5,6] Recently, complexes between boron and sugars have become a lynchpin for the development of synthetic ...
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    Boron-polyol interactions are of fundamental importance to human health [1], plant growth [2] and quorum sensing among certain bacteria [3]. Such diversity is perhaps not surprising when one considers boron is one of the ten most abundant elements in sea water and carbohydrates make up the planet’s most abundant class of biomass. Several boronic acids matrices are commercially available for the purification of glycoproteins by affinity chromatography [4], and boronic acids are also useful carbohydrate protecting groups.[5,6] Recently, complexes between boron and sugars have become a lynchpin for the development of synthetic carbohydrate receptors.[7] These complexes involve covalent interactions that are reversible in aqueous solution. This chapter reviews current understanding of these processes, provides a historical perspective on their discovery, identifies methods for studying these complexes and classifies these interactions by carbohydrate type. Such information is key to the design and synthesis of synthetic lectins, also termed “boronolectins” when containing boron [7].
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    Book Title
    Carbohydrates - Comprehensive Studies on Glycobiology and Glycotechnology
    Publisher URI
    http://www.intechopen.com/
    DOI
    https://doi.org/10.5772/50630
    Copyright Statement
    Copyright 2012 Houston et al., licensee InTech. This is an open access chapter distributed under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/3.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited.
    Subject
    Organic Chemistry not elsewhere classified
    Publication URI
    http://hdl.handle.net/10072/50324
    Collection
    • Book chapters

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