Stereocontrolled Synthesis of the cis-Hydroxydecalin System: Towards Biologically Active 19-nor-clerodanes
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The 19-nor-clerodanes are compact, densely functionalized diterpenes based on a stereocentre-rich decalin scaffold. To date only a few examples of the 19-nor-clerodanes have been synthesized, hence new flexible strategies are required. We herein describe the stereocontrolled construction of the cis-hydroxy decalin core in a concise fashion.
European Journal of Organic Chemistry
Organic Chemical Synthesis