Dichlorido[2-(3,5-dimethyl-1H-pyrazol-1-yl-[kappa]N2)quinoline-[kappa]N]zinc
View/ Open
Author(s)
Hidayat bin Najib, Muhd.
Tan, Ai Ling
Young, David
Ng, Seik Weng
Tiekink, Edward R. T.
Griffith University Author(s)
Year published
2012
Metadata
Show full item recordAbstract
The ZnII atom in the title compound, [ZnCl2(C14H13N3)], is coordinated by a Cl2N2 donor set defined by quinoline and pyrazole N atoms of the chelating ligand and two Cl atoms. Distortions from the ideal tetrahedral geometry relate to the restricted bite angle of the chelating ligand [N-Zn-N = 78.54 (12)°]. In the crystal, molecules are connected into a three-dimensional structure by C-H...Cl interactions, involving both Cl atoms, and [pi]-[pi] interactions that occur between the pyrazole ring and each of the pyridine and benzene rings of the quinoline residue [intercentroid distances = 3.655 (2) and 3.676 (2) Å].The ZnII atom in the title compound, [ZnCl2(C14H13N3)], is coordinated by a Cl2N2 donor set defined by quinoline and pyrazole N atoms of the chelating ligand and two Cl atoms. Distortions from the ideal tetrahedral geometry relate to the restricted bite angle of the chelating ligand [N-Zn-N = 78.54 (12)°]. In the crystal, molecules are connected into a three-dimensional structure by C-H...Cl interactions, involving both Cl atoms, and [pi]-[pi] interactions that occur between the pyrazole ring and each of the pyridine and benzene rings of the quinoline residue [intercentroid distances = 3.655 (2) and 3.676 (2) Å].
View less >
View less >
Journal Title
Acta Crystallographica. Section E: Structure Reports Online
Volume
E68
Issue
5
Copyright Statement
© The Author(s) 2012. For information about this journal please refer to the journal’s website. All articles published in Acta Crystallographica Section E are open access and distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. See http://creativecommons.org/licenses/by/2.0/uk/legalcode
Subject
Organic Chemical Synthesis
Chemical Sciences