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  • Growth of large single MOF crystals and effective separation of organic dyes

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    Author(s)
    Li, Lina
    Sun, Fuxing
    Jia, Jiangtao
    Borjigin, Tsolmon
    Zhu, Guangshan
    Griffith University Author(s)
    Zhu, Guangshan
    Year published
    2013
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    Abstract
    Through the optimization of synthesis conditions, we obtained large Cu-3(BTC)(2) crystals with a diameter of 2-4 mm. Such large crystals could be utilized as "chromatographic columns" for effective separation of organic dyes such as thionine (TH) and pyronin B (PB). It was found that the concentration of hydron was the key factor to obtain the large pure crystals. This strategy could be used to grow other hydrophilic MOFs.Through the optimization of synthesis conditions, we obtained large Cu-3(BTC)(2) crystals with a diameter of 2-4 mm. Such large crystals could be utilized as "chromatographic columns" for effective separation of organic dyes such as thionine (TH) and pyronin B (PB). It was found that the concentration of hydron was the key factor to obtain the large pure crystals. This strategy could be used to grow other hydrophilic MOFs.
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    Journal Title
    Cryst Eng Comm
    Volume
    15
    Issue
    20
    DOI
    https://doi.org/10.1039/c3ce40137e
    Copyright Statement
    © 2013 Royal Society of Chemistry. This is the author-manuscript version of this paper. Reproduced in accordance with the copyright policy of the publisher. Please refer to the journal website for access to the definitive, published version.
    Subject
    Inorganic chemistry
    Transition metal chemistry
    Physical chemistry
    Materials engineering
    Publication URI
    http://hdl.handle.net/10072/53446
    Collection
    • Journal articles

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