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  • A luminescent metal-organic framework for sensing methanol in ethanol solution

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    89485_1.pdf (412.5Kb)
    Author(s)
    Jin, Zhao
    He, Hongming
    Zhao, Huanyu
    Borjigin, Tsolmon
    Sun, Fuxing
    Zhang, Daming
    Zhu, Guangshan
    Griffith University Author(s)
    Zhu, Guangshan
    Zhao, Huanyu
    Year published
    2013
    Metadata
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    Abstract
    A new luminescent Zn-MOF has been synthesized under hydrothermal condition using a semi-rigid ligand H3pcoip (4-(2-carboxyphenoxy)isophthalic acid) is reported. The luminescence properties of 1 in methanol, ethanol, and water have been investigated. Interestingly, compound 1 has a unique response to methanol compared to ethanol and water. Moreover, 1 displays a turn-on switching property triggered by methanol solvent molecules and a high sensitivity towards methanol concentration as low as 2 נ10-7(VMeOH/Vtotal) in ethanol solution. The results indicate that the Zn-MOF has potential application as a sensor for ...
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    A new luminescent Zn-MOF has been synthesized under hydrothermal condition using a semi-rigid ligand H3pcoip (4-(2-carboxyphenoxy)isophthalic acid) is reported. The luminescence properties of 1 in methanol, ethanol, and water have been investigated. Interestingly, compound 1 has a unique response to methanol compared to ethanol and water. Moreover, 1 displays a turn-on switching property triggered by methanol solvent molecules and a high sensitivity towards methanol concentration as low as 2 נ10-7(VMeOH/Vtotal) in ethanol solution. The results indicate that the Zn-MOF has potential application as a sensor for detecting methanol in ethanol solution with excellent selectivity and high sensitivity.
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    Journal Title
    Dalton Transactions
    Volume
    42
    Issue
    37
    DOI
    https://doi.org/10.1039/c3dt51414e
    Copyright Statement
    © 2013 Royal Society of Chemistry. This is the author-manuscript version of this paper. Reproduced in accordance with the copyright policy of the publisher. Please refer to the journal website for access to the definitive, published version.
    Subject
    Transition Metal Chemistry
    Inorganic Chemistry
    Theoretical and Computational Chemistry
    Other Chemical Sciences
    Publication URI
    http://hdl.handle.net/10072/54811
    Collection
    • Journal articles

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