dc.contributor.author | Battle, Andrew R | |
dc.contributor.author | Edwards, Peter G | |
dc.contributor.author | Haigh, Robert | |
dc.contributor.author | Hibbs, David E | |
dc.contributor.author | Li, Dongmei | |
dc.contributor.author | Liddiard, Sam M | |
dc.contributor.author | Newman, Paul D | |
dc.date.accessioned | 2017-05-03T16:04:25Z | |
dc.date.available | 2017-05-03T16:04:25Z | |
dc.date.issued | 2007 | |
dc.date.modified | 2013-12-12T03:09:02Z | |
dc.identifier.issn | 0276-7333 | |
dc.identifier.doi | 10.1021/om060798g | |
dc.identifier.uri | http://hdl.handle.net/10072/54872 | |
dc.description.abstract | The complex [(?5-Me3SiC5H4)Fe(10aneP3-H2,C2H3)]+, where Me3SiC5H4 is trimethylsilylcyclopentadienyl and 10-aneP3-H2,C2H3 is 1-vinyl-1,4,8-triphosphacyclodecane, has been prepared by the base-catalyzed template cyclization of 1,3-bis(phosphino)propane (1,3-bpp) and trivinylphosphine (tvp) at the metal center. A related radical-initiated iron-template reaction between 1,2-bis(phosphino)ethane (1,2-bpe) and triallylphosphine (tap) gave [(?5-C5Me5)Fe(Me-10aneP3-H2,C3H5)]+, where C5Me5 is 1,2,3,4,5-pentamethylcyclopentadienyl and Me-10aneP3-H2,C3H5 is the unsymmetric 10-aneP3 derivative 1-allyl-3-methyl-1,4,7-triphosphacyclodecane. This macrocycle is the result of two intramolecular hydrophosphination reactions, one that generates a five-membered (chelate) ring with an exo-methyl group and one a six-membered chelate. The [(?5-CpR)Fe]+ fragment also controls the cyclization of 1,2-bis(diallylphosphino)ethane with phenylphosphine to give a ternary complex containing the symmetrical 11-membered macrocycle 1-phenyl-4,8-diallyl-1,4,8-triphosphacycloundecane, in addition to the unsymmetrical 10-aneP3 derivative. | |
dc.description.peerreviewed | Yes | |
dc.description.publicationstatus | Yes | |
dc.language | English | |
dc.language.iso | eng | |
dc.publisher | American Chemical Society | |
dc.publisher.place | United States | |
dc.relation.ispartofstudentpublication | N | |
dc.relation.ispartofpagefrom | 377 | |
dc.relation.ispartofpageto | 386 | |
dc.relation.ispartofissue | 2 | |
dc.relation.ispartofjournal | Organometallics | |
dc.relation.ispartofvolume | 26 | |
dc.rights.retention | Y | |
dc.subject.fieldofresearch | Inorganic chemistry | |
dc.subject.fieldofresearch | Organic chemistry | |
dc.subject.fieldofresearch | Other chemical sciences | |
dc.subject.fieldofresearch | Organometallic chemistry | |
dc.subject.fieldofresearchcode | 3402 | |
dc.subject.fieldofresearchcode | 3405 | |
dc.subject.fieldofresearchcode | 3499 | |
dc.subject.fieldofresearchcode | 340209 | |
dc.title | Synthesis and Characterization of Iron(II) Complexes of 10- and 11-Membered Triphosphamacrocycles | |
dc.type | Journal article | |
dc.type.description | C1 - Articles | |
dc.type.code | C - Journal Articles | |
gro.rights.copyright | Self-archiving of the author-manuscript version is not yet supported by this journal. Please refer to the journal link for access to the definitive, published version or contact the author[s] for more information. | |
gro.date.issued | 2007 | |
gro.hasfulltext | No Full Text | |
gro.griffith.author | Battle, Andrew | |