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dc.contributor.authorBattle, Andrew R
dc.contributor.authorEdwards, Peter G
dc.contributor.authorHaigh, Robert
dc.contributor.authorHibbs, David E
dc.contributor.authorLi, Dongmei
dc.contributor.authorLiddiard, Sam M
dc.contributor.authorNewman, Paul D
dc.date.accessioned2017-05-03T16:04:25Z
dc.date.available2017-05-03T16:04:25Z
dc.date.issued2007
dc.date.modified2013-12-12T03:09:02Z
dc.identifier.issn0276-7333
dc.identifier.doi10.1021/om060798g
dc.identifier.urihttp://hdl.handle.net/10072/54872
dc.description.abstractThe complex [(?5-Me3SiC5H4)Fe(10aneP3-H2,C2H3)]+, where Me3SiC5H4 is trimethylsilylcyclopentadienyl and 10-aneP3-H2,C2H3 is 1-vinyl-1,4,8-triphosphacyclodecane, has been prepared by the base-catalyzed template cyclization of 1,3-bis(phosphino)propane (1,3-bpp) and trivinylphosphine (tvp) at the metal center. A related radical-initiated iron-template reaction between 1,2-bis(phosphino)ethane (1,2-bpe) and triallylphosphine (tap) gave [(?5-C5Me5)Fe(Me-10aneP3-H2,C3H5)]+, where C5Me5 is 1,2,3,4,5-pentamethylcyclopentadienyl and Me-10aneP3-H2,C3H5 is the unsymmetric 10-aneP3 derivative 1-allyl-3-methyl-1,4,7-triphosphacyclodecane. This macrocycle is the result of two intramolecular hydrophosphination reactions, one that generates a five-membered (chelate) ring with an exo-methyl group and one a six-membered chelate. The [(?5-CpR)Fe]+ fragment also controls the cyclization of 1,2-bis(diallylphosphino)ethane with phenylphosphine to give a ternary complex containing the symmetrical 11-membered macrocycle 1-phenyl-4,8-diallyl-1,4,8-triphosphacycloundecane, in addition to the unsymmetrical 10-aneP3 derivative.
dc.description.peerreviewedYes
dc.description.publicationstatusYes
dc.languageEnglish
dc.language.isoeng
dc.publisherAmerican Chemical Society
dc.publisher.placeUnited States
dc.relation.ispartofstudentpublicationN
dc.relation.ispartofpagefrom377
dc.relation.ispartofpageto386
dc.relation.ispartofissue2
dc.relation.ispartofjournalOrganometallics
dc.relation.ispartofvolume26
dc.rights.retentionY
dc.subject.fieldofresearchInorganic chemistry
dc.subject.fieldofresearchOrganic chemistry
dc.subject.fieldofresearchOther chemical sciences
dc.subject.fieldofresearchOrganometallic chemistry
dc.subject.fieldofresearchcode3402
dc.subject.fieldofresearchcode3405
dc.subject.fieldofresearchcode3499
dc.subject.fieldofresearchcode340209
dc.titleSynthesis and Characterization of Iron(II) Complexes of 10- and 11-Membered Triphosphamacrocycles
dc.typeJournal article
dc.type.descriptionC1 - Articles
dc.type.codeC - Journal Articles
gro.rights.copyrightSelf-archiving of the author-manuscript version is not yet supported by this journal. Please refer to the journal link for access to the definitive, published version or contact the author[s] for more information.
gro.date.issued2007
gro.hasfulltextNo Full Text
gro.griffith.authorBattle, Andrew


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