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  • Solvent-directed synthesis of chiral and non-centrosymmetric metal–organic frameworks based on pyridine-3,5-dicarboxylate

    Author(s)
    Sun, Fuxing
    Zhu, Guangshan
    Griffith University Author(s)
    Zhu, Guangshan
    Year published
    2013
    Metadata
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    Abstract
    Three new metal–organic frameworks Mn(3,5-PDC)(H2O)•(glycol) (JUC-58), M(3,5-PDC)(H2O)(glycol)•(H2O) (JUC-59-M, M = Co, Ni), have been synthesized by the assembly of tri-connected ligand pyridine-3,5-dicarboxylic acid (3,5-PDC) and different metals under the solvothermal condition in DMF and glycol. JUC-58 is an unusual example of 3-D chiral MOF with helical channels, while JUC-59-Co and JUC-59-Ni are isostructural and have non-centrosymmetric structures with a very rare 3-connected non-interpenetrated lig-b net. It is worth noting that glycol could play an important role in the formation and stabilization of these networks.Three new metal–organic frameworks Mn(3,5-PDC)(H2O)•(glycol) (JUC-58), M(3,5-PDC)(H2O)(glycol)•(H2O) (JUC-59-M, M = Co, Ni), have been synthesized by the assembly of tri-connected ligand pyridine-3,5-dicarboxylic acid (3,5-PDC) and different metals under the solvothermal condition in DMF and glycol. JUC-58 is an unusual example of 3-D chiral MOF with helical channels, while JUC-59-Co and JUC-59-Ni are isostructural and have non-centrosymmetric structures with a very rare 3-connected non-interpenetrated lig-b net. It is worth noting that glycol could play an important role in the formation and stabilization of these networks.
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    Journal Title
    Inorganic Chemistry Communications
    Volume
    38
    DOI
    https://doi.org/10.1016/j.inoche.2013.10.018
    Subject
    Inorganic Chemistry not elsewhere classified
    Inorganic Chemistry
    Other Chemical Sciences
    Publication URI
    http://hdl.handle.net/10072/57026
    Collection
    • Journal articles

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