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  • Adenosinium 3,5-dinitrosalicylate

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    Author(s)
    Smith, G
    Wermuth, UD
    Healy, PC
    Griffith University Author(s)
    Healy, Peter C.
    Wermuth, Urs D.
    Year published
    2004
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    Abstract
    The crystal structure of adenosinium 3,5-dinitrosalicylicate, C10H14N5O4+烷H3N2O7-, shows the presence of a primary chain structure formed through homomeric head-to-tail cyclic R22(10) hydrogen-bonding interactions between hydroxy O- and both purine and amine N-donor and acceptor groups of the furanose and purine moieties of the adenosinium species. These chain structures are related by crystallographic 21 symmetry. Secondary hetero-ionic hydrogen bonding, involving the 3,5-dinitrosalicylate anion, including a cyclic R22(8) interaction between the carboxylate group and the protonated purine and amine groups of the adenosinium ...
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    The crystal structure of adenosinium 3,5-dinitrosalicylicate, C10H14N5O4+烷H3N2O7-, shows the presence of a primary chain structure formed through homomeric head-to-tail cyclic R22(10) hydrogen-bonding interactions between hydroxy O- and both purine and amine N-donor and acceptor groups of the furanose and purine moieties of the adenosinium species. These chain structures are related by crystallographic 21 symmetry. Secondary hetero-ionic hydrogen bonding, involving the 3,5-dinitrosalicylate anion, including a cyclic R22(8) interaction between the carboxylate group and the protonated purine and amine groups of the adenosinium cation are also present, together with heteromolecular - interactions giving a three-dimensional hydrogen-bonded polymer structure.
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    Journal Title
    Acta Crystallographica. Section E: Structure reports online
    Volume
    E60
    Issue
    9
    Publisher URI
    http://journals.iucr.org/e/journalhomepage.html
    DOI
    https://doi.org/10.1107/S1600536804019920
    Copyright Statement
    © The Author(s) 2004. For information about this journal please refer to the journal's website. All articles published in Acta Crystallographica Section E are open access and distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. See http://creativecommons.org/licenses/by/2.0/uk/legalcode
    Subject
    History and Archaeology
    Publication URI
    http://hdl.handle.net/10072/5771
    Collection
    • Journal articles

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