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dc.contributor.authorBott, RC
dc.contributor.authorHealy, PC
dc.contributor.authorSmitha, G
dc.date.accessioned2017-05-03T11:09:54Z
dc.date.available2017-05-03T11:09:54Z
dc.date.issued2004
dc.identifier.issn0004-9425
dc.identifier.doi10.1071/CH03172
dc.identifier.urihttp://hdl.handle.net/10072/5772
dc.description.abstractTwo-coordinate tris(2-methylphenyl)phosphine and tris(4-methylphenyl)phosphinegold(I) halide complexes, [AuP(otol)3X], [AuP(ptol)3X], where X = Cl, Br, and I, have been crystallized from dimethylformamide and characterized by single-crystal X-ray structure determinations. The P(otol)3 structures comprise an isomorphous series distinct from the previously published chloride, crystallizing with two independent molecules in the asymmetric unit in the space group Pbca, with a 蠲0.0, b 蠲8.0, c 蠱4.0 Ů The molecules associate to form dimers through a back-to-back sextuple phenyl embrace (6PE). The P(ptol)3 complexes are isomorphous with the previously published chloride, crystallizing with two independent molecules in the unit cell in the space group P21/c, with a 蠱0.0, b 蠲2.0, c 蠱9.5 Ŭ ߠ蠹9஠The molecules associate through edge-to-face interactions along the direction of the a-axis. Preparation of the chloride by anodic dissolution of gold in an acetonitrile solution of the ligand and aqueous HCl yields a new polymorph, crystallizing in the space group Aba2, with a 19.738(2), b 11.813(3), c 17.645(1) Ů Despite the bulkiness of the phosphine ligand, this form of [AuP(ptol)3Cl] exhibits a short intermolecular Au偵 contact distance of 3.375(1) Ŭ indicative of a significant aurophilic interaction. The ranges for the Au-P, Au-Cl, Au-Br, Au-I bond lengths and P-Au-X bond angles in the series are: 2.201(3)-2.265(4), 2.255(3)-2.290(4), 2.388(2)-2.411(2), 2.542(1)-2.556(2) Ŭ and 173.2(2)-179.6(1)࠲espectively.
dc.description.peerreviewedYes
dc.description.publicationstatusYes
dc.languageEnglish
dc.language.isoeng
dc.publisherCSIRO Publishing
dc.publisher.placeAustralia
dc.relation.ispartofpagefrom213
dc.relation.ispartofpageto218
dc.relation.ispartofissue3
dc.relation.ispartofjournalAustralian Journal of Chemistry
dc.relation.ispartofvolume57
dc.subject.fieldofresearchChemical sciences
dc.subject.fieldofresearchcode34
dc.titleEvidence for Au(I)...Au(I) interactions in a sterically congested environment: two-coordinate gold(I) halide phosphine complexes
dc.typeJournal article
dc.type.descriptionC1 - Articles
dc.type.codeC - Journal Articles
gro.date.issued2015-05-21T05:26:19Z
gro.hasfulltextNo Full Text
gro.griffith.authorHealy, Peter C.
gro.griffith.authorBott, Raymond
gro.griffith.authorSmith, Graham


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