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  • Synthesis of lactose-based S-linked sialylmimetics of alpha(2,3)-sialosides.

    Author(s)
    Liakatos, A
    Kiefel, MJ
    von Itzstein, M
    Griffith University Author(s)
    von Itzstein, Mark
    Kiefel, Milton
    Liakatos, Angela
    Year published
    2003
    Metadata
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    Abstract
    A new approach toward the synthesis of lactose-based S-linked sialylmimetics of a(2,3)-linked sialosides is described. These compounds, represented by the general structure 3, were prepared from methyl ߭d-lactoside in 11 steps. It was found that the choice of protecting group was crucial to allow the efficient introduction of sulfur at the 3-position of the galactose ring.A new approach toward the synthesis of lactose-based S-linked sialylmimetics of a(2,3)-linked sialosides is described. These compounds, represented by the general structure 3, were prepared from methyl ߭d-lactoside in 11 steps. It was found that the choice of protecting group was crucial to allow the efficient introduction of sulfur at the 3-position of the galactose ring.
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    Journal Title
    Organic Letters
    Volume
    5
    Issue
    23
    Publisher URI
    http://pubs.acs.org/journal/orlef7
    DOI
    https://doi.org/10.1021/ol035733d
    Copyright Statement
    © 2003 American Chemical Society. Self-archiving of the author-manuscript version is not yet supported by this publisher. Please refer to the journal link for access to the definitive, published version or contact the author for more information.
    Subject
    Chemical sciences
    Publication URI
    http://hdl.handle.net/10072/5841
    Collection
    • Journal articles

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