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dc.contributor.authorV. Bernhardt, Paul
dc.contributor.authorL. Creevey, Nicole
dc.date.accessioned2017-05-03T15:39:32Z
dc.date.available2017-05-03T15:39:32Z
dc.date.issued2004
dc.date.modified2014-06-18T05:56:53Z
dc.identifier.issn14779226
dc.identifier.doi10.1039/B400538D
dc.identifier.urihttp://hdl.handle.net/10072/60551
dc.description.abstractThe syntheses and characterization of two new redox active cyclam ligands ferrocenylmethyl-(6-methyl-1,4,8,11-tetraazacyclotetradec-6-yl)-amine (L3) and 1,1'-ferrocenylmethyl-bis(6-methyl-1,4,8,11-tetraazacyclotetradec-6-yl)-amine (L4) are reported. The compounds each possess a ferrocenyl group bearing one (L3) or two (L4) appended macrocycles linked by their exocyclic amino groups and the crystal structures of both compounds have been determined. Anion binding of L3 and L4 was investigated by electrochemical titrations where H-bonding to each macrocycle causing a shift in the Fc+/0 redox potential was used as a reporter of guest binding. The ZnII complex of L3 has also been isolated and characterized structurally. These compounds were analysed for their capacity to electrochemically recognize anions in both aqueous and non-aqueous solution. We have found that L3, L4 and [ZnL3]2+ sense Cl- and AcO- anions in MeCN-CH2Cl2, a function that is lost in aqueous solution.
dc.description.peerreviewedYes
dc.description.publicationstatusYes
dc.languageEnglish
dc.publisherRSC Publishing
dc.publisher.placeUnited Kingdom
dc.relation.ispartofpagefrom914
dc.relation.ispartofpageto920
dc.relation.ispartofjournalDalton Transactions
dc.relation.ispartofvolume6
dc.subject.fieldofresearchTransition Metal Chemistry
dc.subject.fieldofresearchInorganic Chemistry
dc.subject.fieldofresearchTheoretical and Computational Chemistry
dc.subject.fieldofresearchOther Chemical Sciences
dc.subject.fieldofresearchcode030207
dc.subject.fieldofresearchcode0302
dc.subject.fieldofresearchcode0307
dc.subject.fieldofresearchcode0399
dc.titleElectrochemical anion recognition with ferrocene functionalized macrocycles.
dc.typeJournal article
dc.type.descriptionC1 - Articles
dc.type.codeC - Journal Articles
gro.hasfulltextNo Full Text
gro.griffith.authorKnight, Nicole


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