Bromo[(diphenylphosphino-kP)(diphenylphosphinoyl)methane]gold(I) acetonitrile solvate

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Williams, Michael
Boyd, Sue
Dunstan, Sam
Slade, Debbie
Healy, Peter
Year published
2003
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Abstract
In the title compound, [AuBr(dppmO)]烈3CN [dppmO = Ph2P(CH2)P(O)Ph2], the dppmO ligand coordinates through the P donor to give a linear two-coordinate P-Au-Br gold(I) complex. The Au-Br and Au-P bond lengths are 2.241 (2) and 2.4069 (19) Ŭ respectively. The P-Au-Br and P=O groups lie almost parallel to each other [O-PP-Au = 8.3 (2)ݬ while the intramolecular AuO distance is 3.274 (4) Ů
Journal Title
Acta Crystallographica. Section E: Structure reports online
Volume
E59
Issue
9
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© The Author(s) 2003 For information about this journal please refer to the journal's website. All articles published in Acta Crystallographica Section E are open access and distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. See http://creativecommons.org/licenses/by/2.0/uk/legalcode
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