Bromo[(diphenylphosphino-kP)(diphenylphosphinoyl)methane]gold(I) acetonitrile solvate

In the title compound, [AuBr(dppmO)]烈3CN [dppmO = Ph2P(CH2)P(O)Ph2], the dppmO ligand coordinates through the P donor to give a linear two-coordinate P-Au-Br gold(I) complex. The Au-Br and Au-P bond lengths are 2.241 (2) and 2.4069 (19) Ŭ respectively. The P-Au-Br and P=O groups lie almost parallel to each other [O-PP-Au = 8.3 (2)ݬ while the intramolecular AuO distance is 3.274 (4) ŮIn the title compound, [AuBr(dppmO)]烈3CN [dppmO = Ph2P(CH2)P(O)Ph2], the dppmO ligand coordinates through the P donor to give a linear two-coordinate P-Au-Br gold(I) complex. The Au-Br and Au-P bond lengths are 2.241 (2) and 2.4069 (19) Ŭ respectively. The P-Au-Br and P=O groups lie almost parallel to each other [O-PP-Au = 8.3 (2)ݬ while the intramolecular AuO distance is 3.274 (4) Ů
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Journal Title

Acta Crystallographica. Section E: Structure reports online

Volume

E59

Issue

Publisher URI

http://journals.iucr.org/e/journalhomepage.html

DOI

https://doi.org/10.1107/S1600536803017732

Copyright Statement

© The Author(s) 2003 For information about this journal please refer to the journal's website. All articles published in Acta Crystallographica Section E are open access and distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. See http://creativecommons.org/licenses/by/2.0/uk/legalcode

Subject

Chemical sciences

Publication URI

http://hdl.handle.net/10072/6293

Collection

Journal articles