A new polymorph of u-bis(diphenylphosphino)methane-k2 P:P'-bis[chlorogold(I)]
Abstract
The title compound, [(AuCl)2(dppm)] (dppm = Ph2P(CH2)PPh2), has been found to crystallize as a new triclinic polymorph. Unlike the previously reported monoclinic form, there are no aurophilic AuAu interactions between the Au(I) atoms.
Journal Title
ACTA Crystallographica Section E - Structure Reports Online
Volume
59
Publisher URI
Copyright Statement
© The Author(s) 2003 For information about this journal please refer to the journal's website. All articles published in Acta Crystallographica Section E are open access and distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. See http://creativecommons.org/licenses/by/2.0/uk/legalcode
Subject
Chemical sciences