dc.contributor.author | Loughlin, Wendy | |
dc.contributor.author | Haynes, R. | |
dc.date.accessioned | 2017-05-03T13:34:58Z | |
dc.date.available | 2017-05-03T13:34:58Z | |
dc.date.issued | 1995 | |
dc.identifier.issn | 00049425 | |
dc.identifier.doi | 10.1071/CH9950651 | |
dc.identifier.uri | http://hdl.handle.net/10072/68082 | |
dc.description.abstract | The preparation of some novel four-carbon electrophiles and electrophile intermediates is described. Thus, the chlorobutenyl sulfone (5), the iodobutynyl sulfone (6) and the hitherto unreported chlorobutynyl sulfone (4) were prepared. The novel intermediates, containing a chelating imidazolyl functionality, the N- methylimidazolyl sulfides (13)-(15) were also prepared. However, they polmerized rapidly, thus preventing further synthetic manipulations. The preparation of the a-( trimethylsilyl ) butadienyl sulfones (17) and (18) is described and the mode of formation of the intermediate a- trimethylsilyl sulfides (21) and (22) from the trimethylsilylbutenyl sulfide (27) is discussed. | |
dc.description.peerreviewed | Yes | |
dc.description.publicationstatus | Yes | |
dc.language | English | |
dc.language.iso | eng | |
dc.publisher | CSIRO Publishing | |
dc.publisher.place | Australia | |
dc.relation.ispartofpagefrom | 651 | |
dc.relation.ispartofpageto | 661 | |
dc.relation.ispartofjournal | Australian Journal of Chemistry | |
dc.relation.ispartofvolume | 48 | |
dc.subject.fieldofresearch | Chemical sciences | |
dc.subject.fieldofresearchcode | 34 | |
dc.title | Preparation of Some Novel Butyl, Butenyl, Butadienyl and Butynyl Sulfone Electrophiles for Use in Enolate Trapping Studies | |
dc.type | Journal article | |
dc.type.description | C1 - Articles | |
dc.type.code | C - Journal Articles | |
gro.hasfulltext | No Full Text | |
gro.griffith.author | Loughlin, Wendy A. | |