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  • Two for one: structure revision of the marine sesterterpene tetronic acid strobilinin to (8Z,13E,20Z)-strobilinin and (8E,13Z,20Z)-strobilinin

    Author(s)
    DAVIS, R
    CAPON, RJ
    Griffith University Author(s)
    Davis, Rohan A.
    Year published
    1994
    Metadata
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    Abstract
    A reinvestigation of the known marine natural product strobilinin I (R = H) has revealed it not to be a single compd., but to consist of two naturally occurring geometric isomers. (8E,13Z,20Z)- and (8Z,13E,20Z)-strobilinin I (R = Ac) were resolved, characterized, and their structures assigned by spectroscopic anal. It would appear that the abs. stereochem. of the strobilinins is very likely opposite to that of co-occurring variabilin .A reinvestigation of the known marine natural product strobilinin I (R = H) has revealed it not to be a single compd., but to consist of two naturally occurring geometric isomers. (8E,13Z,20Z)- and (8Z,13E,20Z)-strobilinin I (R = Ac) were resolved, characterized, and their structures assigned by spectroscopic anal. It would appear that the abs. stereochem. of the strobilinins is very likely opposite to that of co-occurring variabilin .
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    Journal Title
    Australian Journal of Chemistry
    Volume
    47
    DOI
    https://doi.org/10.1071/CH9940933
    Subject
    Chemical Sciences
    Publication URI
    http://hdl.handle.net/10072/68085
    Collection
    • Journal articles

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