dc.contributor.author | Zhao, Nian | |
dc.contributor.author | Sun, Fuxing | |
dc.contributor.author | Zhang, Shixing | |
dc.contributor.author | He, Hongming | |
dc.contributor.author | Liu, Jia | |
dc.contributor.author | Li, Qin | |
dc.contributor.author | Zhu, Guangshan | |
dc.date.accessioned | 2017-05-03T16:05:13Z | |
dc.date.available | 2017-05-03T16:05:13Z | |
dc.date.issued | 2015 | |
dc.identifier.issn | 0020-1669 | |
dc.identifier.doi | 10.1021/ic501560z | |
dc.identifier.uri | http://hdl.handle.net/10072/69582 | |
dc.description.abstract | A new three-dimensional porous metal-organic framework, JUC-119, constructed by a pyrene-based dendritic organic linker, H8TIAPy (H8TIAPy = 1,3,6,8-tetrakis(3,5-isophthalic acid)pyrene), and Eu(III) has been synthesized successfully. JUC-119 shows unexpected stability under a wide range of basic conditions from 0 to 0.01 M NaOH. Furthermore, with two carboxyl groups uncoordinated in each ligand, the crystals of JUC-119 show deprotonation-triggered Stokes shift fluorescence under basic conditions. As the concentration of base increases from 0 to 0.01 M NaOH, the luminescence emission of JUC-119 becomes gradually red shifted from 455 to 485 nm. In addition, the Stokes shift shows a good linear relationship to -log[OH-], which makes JUC-119 promising for base sensing. | |
dc.description.peerreviewed | Yes | |
dc.description.publicationstatus | Yes | |
dc.language | English | |
dc.language.iso | eng | |
dc.publisher | American Chemical Society | |
dc.publisher.place | United States | |
dc.relation.ispartofstudentpublication | N | |
dc.relation.ispartofpagefrom | 65 | |
dc.relation.ispartofpageto | 68 | |
dc.relation.ispartofissue | 1 | |
dc.relation.ispartofjournal | Inorganic Chemistry | |
dc.relation.ispartofvolume | 54 | |
dc.rights.retention | Y | |
dc.subject.fieldofresearch | Inorganic chemistry | |
dc.subject.fieldofresearch | Inorganic chemistry not elsewhere classified | |
dc.subject.fieldofresearch | Physical chemistry | |
dc.subject.fieldofresearch | Other chemical sciences | |
dc.subject.fieldofresearchcode | 3402 | |
dc.subject.fieldofresearchcode | 340299 | |
dc.subject.fieldofresearchcode | 3406 | |
dc.subject.fieldofresearchcode | 3499 | |
dc.title | Deprotonation-Triggered Stokes Shift Fluorescence of an Unexpected Basic-Stable Metal−Organic Framework | |
dc.type | Journal article | |
dc.type.description | C1 - Articles | |
dc.type.code | C - Journal Articles | |
gro.hasfulltext | No Full Text | |
gro.griffith.author | Li, Qin | |