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  • Fluorescent Dodecapus in 3D Framework

    Author(s)
    He, Hongming
    Sun, Fuxing
    Jia, Jiangtao
    Bian, Zheng
    Zhao, Nian
    Qiu, Xuepeng
    Gao, Lianxun
    Zhu, Guangshan
    Griffith University Author(s)
    Zhu, Guangshan
    Year published
    2014
    Metadata
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    Abstract
    A dendritic aromatic 12-carboxyl ligand (H12TDDPB) is assembled with Zn(II) ion. The TDDPB dimer coordinated with 12 Zn(II) ions, regarded as a dodecapus, is stabilized by metal coordination and p-p stacking. The dodecapus-based framework presents a new type of topology (hhm) with the point symbol of (6縷10)3(63縷10籲)3(63)7. The resulting material emits strong blue luminescence in DMF, while the maximum emission of free ligand H12TDDPB is in the ultraviolet region.A dendritic aromatic 12-carboxyl ligand (H12TDDPB) is assembled with Zn(II) ion. The TDDPB dimer coordinated with 12 Zn(II) ions, regarded as a dodecapus, is stabilized by metal coordination and p-p stacking. The dodecapus-based framework presents a new type of topology (hhm) with the point symbol of (6縷10)3(63縷10籲)3(63)7. The resulting material emits strong blue luminescence in DMF, while the maximum emission of free ligand H12TDDPB is in the ultraviolet region.
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    Journal Title
    Crystal Growth & Design
    Volume
    14
    Issue
    9
    DOI
    https://doi.org/10.1021/cg501012e
    Subject
    Inorganic chemistry
    Physical chemistry
    Materials engineering
    Other engineering not elsewhere classified
    Publication URI
    http://hdl.handle.net/10072/69824
    Collection
    • Journal articles

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