Fluorescent Dodecapus in 3D Framework
Author(s)
He, Hongming
Sun, Fuxing
Jia, Jiangtao
Bian, Zheng
Zhao, Nian
Qiu, Xuepeng
Gao, Lianxun
Zhu, Guangshan
Griffith University Author(s)
Year published
2014
Metadata
Show full item recordAbstract
A dendritic aromatic 12-carboxyl ligand (H12TDDPB) is assembled with Zn(II) ion. The TDDPB dimer coordinated with 12 Zn(II) ions, regarded as a dodecapus, is stabilized by metal coordination and p-p stacking. The dodecapus-based framework presents a new type of topology (hhm) with the point symbol of (6縷10)3(63縷10籲)3(63)7. The resulting material emits strong blue luminescence in DMF, while the maximum emission of free ligand H12TDDPB is in the ultraviolet region.A dendritic aromatic 12-carboxyl ligand (H12TDDPB) is assembled with Zn(II) ion. The TDDPB dimer coordinated with 12 Zn(II) ions, regarded as a dodecapus, is stabilized by metal coordination and p-p stacking. The dodecapus-based framework presents a new type of topology (hhm) with the point symbol of (6縷10)3(63縷10籲)3(63)7. The resulting material emits strong blue luminescence in DMF, while the maximum emission of free ligand H12TDDPB is in the ultraviolet region.
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Journal Title
Crystal Growth & Design
Volume
14
Issue
9
Subject
Inorganic chemistry
Physical chemistry
Materials engineering
Other engineering not elsewhere classified