dc.contributor.author | Loughlin, WA | |
dc.contributor.author | Rowen, CC | |
dc.contributor.author | Healy, PC | |
dc.date.accessioned | 2017-06-29T12:31:02Z | |
dc.date.available | 2017-06-29T12:31:02Z | |
dc.date.issued | 2002 | |
dc.date.modified | 2009-08-21T06:37:45Z | |
dc.identifier.issn | 1472-779X | |
dc.identifier.doi | 10.1039/b107705h | |
dc.identifier.uri | http://hdl.handle.net/10072/7028 | |
dc.description.abstract | The enolate generated from cyclohexanone and LDA at -78 àin THF reacts with (ᩭphenyl vinyl sulfoxide to give the novel sulfinylbicyclo[4.2.0]octanols 1-3 and monoalkylated sulfoxide 4. The effects of changes in temperature, concentration, and reaction time were studied. By accurate control of temperature, concentration, and reaction time the ratio of bicyclooctanols 1-3 to monoalkylated sulfoxide 4 obtained was 95 5. The bicyclooctanols 1-3 were characterised as the sulfones 5 and 6. The relative stereochemistries of the bicyclooctanols 1-3 were established by X-ray structural determination. | |
dc.description.peerreviewed | Yes | |
dc.description.publicationstatus | Yes | |
dc.language | English | |
dc.language.iso | eng | |
dc.publisher | Royal Society of Chemistry | |
dc.publisher.place | UK | |
dc.publisher.uri | http://www.rsc.org/Publishing/Journals/P1/ | |
dc.relation.ispartofpagefrom | 296 | |
dc.relation.ispartofpageto | 302 | |
dc.relation.ispartofedition | 2002 | |
dc.relation.ispartofjournal | Journal of the Chemical Society. Perkin Transactions 2 | |
dc.relation.ispartofvolume | 2002 | |
dc.subject.fieldofresearchcode | 250399 | |
dc.title | Investigations into the reaction of the lithium enolate of cyclohexanone and phenyl vinyl sulfoxide: A simple synthesis of a bicyclo[4.2.0]octan-1-ol | |
dc.type | Journal article | |
dc.type.description | C1 - Articles | |
dc.type.code | C - Journal Articles | |
gro.rights.copyright | © 2002 Royal Society of Chemistry. Please refer to the journal link for access to the definitive, published version. | |
gro.date.issued | 2002 | |
gro.hasfulltext | No Full Text | |
gro.griffith.author | Healy, Peter C. | |
gro.griffith.author | Loughlin, Wendy A. | |