Band structure of ZnO from resonant x-ray emission spectroscopy
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Ruck, B.
J Piper, L.
DeMasi, A.
Smith, K.
Schleife, A.
Fuchs, F.
Bechstedt, F.
Chai, J.
Durbin, S.
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Abstract
Soft x-ray emission and absorption spectroscopy of the O?K-edge are employed to investigate the electronic structure of wurtzite ZnO(0001). A quasiparticle band structure calculated within the GW approximation agrees well with the data, most notably with the energetic location of the Zn?3d-O?2p hybridized state and the anisotropy of the absorption spectra. Dispersion in the band structure is mapped using the coherent k-selective part of the resonant x-ray emission spectra. We show that a more extensive mapping of the bands is possible in the case of crystalline anisotropy such as that found in ZnO.
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Physical Review B
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78
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Compound Semiconductors
Physical Sciences
Chemical Sciences
Engineering