Carbene induced rearrangement products from two furoquinolinone scaffolds

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Lindahl, Karl-Fredrik
Carroll, Anthony
Quinn, Ronald J
Ripper, Justin A
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2010
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Abstract

Novel double CH-insertion and rearrangement products (5, 6, and 7) were isolated from treatment of 1 or 2 with dimethyl diazomalonate (3) under dirhodiumtetrakis mediated carbenoid chemistry conditions. A new possible reaction pathway is suggested and discussed. Also other diazo compounds were tested.

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Journal of Heterocyclic Chemistry

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47

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4

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Self-archiving of the author-manuscript version is not yet supported by this journal. Please refer to the journal link for access to the definitive, published version or contact the author[s] for more information.

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Organic chemistry

Organic chemical synthesis

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