Bis[2-(diphenylphosphanyl-kP)-benzaldehyde]iodidogold(I)
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Dunstan, SPC
Healy, PC
Tiekink, ERT
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Abstract
In the title compound, [AuI(C19H15OP)2], the complete molecule is generated by the application of twofold symmetry. The AuI atom is in a trigonal-planar geometry within an IP2 donor set with the greatest distortion seen in the P-Au-P angle [128.49 (3) °]. Close intramolecular Au...O interactions [3.172 (3) Å] are observed. No specific intermolecular interactions are noted in the crystal packing.
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Acta Crystallographica. Section E: Structure Reports Online
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E68
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4
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© The Author(s) 2012. For information about this journal please refer to the journal’s website. All articles published in Acta Crystallographica Section E are open access and distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. See http://creativecommons.org/licenses/by/2.0/uk/legalcode
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Chemical sciences
Transition metal chemistry