Bioaffinity Mass Spectrometry Screening

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Yang, Ben
Feng, Yun Jiang
Vu, Hoan
McCormick, Brendan
Rowley, Jessica
Pedro, Liliana
Crowther, Gregory J
Van Voorhis, Wesley C
Forster, Paul I
Quinn, Ronald J
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2016
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Abstract

Electrospray ionization Fourier transform ion cyclotron resonance mass spectrometry (ESI-FTICR-MS or ESI-FTMS) was used to screen 192 natural product extracts and a 659-member natural product-based fragment library for bindings to a potential malaria drug target, Plasmodium falciparum Rab11a (PfRab11a, PF13_0119). One natural product extract and 11 fragments showed binding activity. A new natural product, arborside E, was identified from the active extract of Psydrax montigena as a weak binder. Its binding activity and inhibitory activity against PfRab11a were confirmed by ESI-FTMS titration experiments and an orthogonal enzyme assay.

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Journal of Biomolecular Screening

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21

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2

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Biochemistry and cell biology

Biochemistry and cell biology not elsewhere classified

Medical biochemistry and metabolomics

Medical biotechnology

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