(Acetato-[kappa]O)(acetato-[kappa]2O,O')[2-(3,5-dimethyl-1H-pyrazol-1-yl-[kappa]N2)quinoline-[kappa]N]zinc(II)
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Tan, Ai Ling
Young, David
Ng, Seik Weng
Tiekink, Edward R. T.
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Abstract
The ZnII atom in the title compound, [Zn(C2H3O2)2(C14H13N3)], is coordinated by an N2O3 donor set defined by the quinolinyl- and pyrazolyl-N atoms of the chelating heterocyclic ligand, and three carboxylate-O atoms derived from the monodentate and bidentate carboxylate ligands. Distortions from the ideal square-pyramidal coordination geometry relate to the restricted bite angle of the chelating ligands, i.e. O-Zn-O = 59.65 (5) and N-Zn-N = 76.50 (6)°, and the close approach of the non-coordinating carbonyl atom [Zn...O = 2.858 (2) Å]. In the crystal, molecules are consolidated into a three-dimensional architecture by C-H...O interactions
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Acta Crystallographica. Section E: Structure Reports Online
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E68
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7
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© The Author(s) 2012. For information about this journal please refer to the journal’s website. All articles published in Acta Crystallographica Section E are open access and distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. See http://creativecommons.org/licenses/by/2.0/uk/legalcode
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Organic Chemical Synthesis
Chemical Sciences