Highly dispersed nickel anchored on a N-doped carbon molecular sieve derived from metal-organic frameworks for efficient hydrodeoxygenation in the aqueous phase
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Author(s)
Hu, Zhi
Chen, Chun
Zhu, Xiaoguang
Zhang, Haimin
Zhang, Yunxia
Zhao, Huijun
Wang, Guozhong
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Abstract
ZIF-8 was employed as a template to synthesize HD-Ni/N-CMS containing highly dispersed Ni at the atomic level anchored on a N-doped carbon molecular sieve for vanillin hydrodeoxygenation. The ZIF-8 structure was inherited and Ni-N bonds were formed by the coordination of Ni with N-rich defects, therefore it exhibited a high turnover frequency (1047.1 h-1) and good stability.
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Chemical communications
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56
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49
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Chemical sciences
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Fan, R; Fan, R; Hu, Z; Hu, Z; Chen, C; Zhu, X; Zhang, H; Zhang, Y; Zhao, H; Zhao, H; Wang, G, Highly dispersed nickel anchored on a N-doped carbon molecular sieve derived from metal-organic frameworks for efficient hydrodeoxygenation in the aqueous phase, Chemical communications, 2020, 56 (49), pp. 6696-6699