(η5-Pentamethylcyclopentadienyl)(η6-p-toluenesulfonamide) ruthenium(II) tetraphenylborate
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Williams, Michael L
Poulsen, Sally-Ann
Healy, Peter C
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Abstract
The crystal structure of the title compound, [Ru(C10H15)(C7H9NO2S)]C24H20B, has been determined as part of our investigation into the structural and biological properties of organometallic RuII-arene-Cp* complex salts of the type [R-PhRuCp*]+瘭 (where Cp* is pentamethylcyclopentadiene). Tethering the RuCp* group to the benzene ring of p-toluenesulfonamide results in only minor changes to the molecular geometry of the sulfonamide, but, together with crystallization as the [BPh4]- salt, effectively blocks involvement of the sulfonamide group in N-H...O hydrogen-bonding networks.
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Acta Crystallographica. Section E: Structure reports online
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E64
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12
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© The Author(s) 2008. For information about this journal please refer to the journal's website. All articles published in Acta Crystallographica Section E are open access and distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. See http://creativecommons.org/licenses/by/2.0/uk/legalcode
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Chemical sciences