A volumetric study of molecular inclusion by α-cyclodextrin
No Thumbnail Available
File version
Author(s)
Isaacs, N.
Young, D.
Young, D.
Griffith University Author(s)
Primary Supervisor
Other Supervisors
Editor(s)
Date
1999
Size
File type(s)
Location
License
Abstract
The reaction volume (Δ V̄ c→0) associated with inclusion of 3-nitrophenol by α-cyclodextrin was determined by densitometry to be −9 cm3 mol−1 while the corresponding value for encapsulation of methyl orange by two molecules of α-cyclodextrin is +27 cm3 mol−1. These volume changes can be interpreted in terms of displacement of solvent from the cavity of α-cyclodextrin and/or changes in solvation of the “guest” molecule.
Journal Title
Tetrahedron Letters
Conference Title
Book Title
Edition
Volume
40
Issue
20
Thesis Type
Degree Program
School
Publisher link
Patent number
Funder(s)
Grant identifier(s)
Rights Statement
Rights Statement
Item Access Status
Note
Access the data
Related item(s)
Subject
Medicinal and Biomolecular Chemistry
Organic Chemistry