Peripherally metallated porphyrins: the first examples of meso-η(1)-palladio(II) and -platinio(II) complexes with chelating diamine ligands
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P. Arnold, Dennis
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Abstract
The oxidative addition of bis(dibenzylideneacetone)platinum(0) to meso-bromo-5,15-diarylporphyrins in the presence of PPh3 has been shown to be an effective way of synthesising eta(1)-organoplatinum porphyrins in high yields. This methodology has been extended to synthesise various palladio- and platinioporphyrins that utilise bidentate nitrogen donor ligands [N,N,N',N'-tetramethylethylenediamine (tmeda) and 2,2'-bipyridyl (bpy)] in order to enforce a cis configuration at the metal centre. The products were characterised by multinuclear NMR and UV-Vis spectroscopy as well as fast-atom bombardment and high-resolution electrospray ionisation mass spectroscopy.
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European journal of inorganic chemistry
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2004
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6
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© 2004 John Wiley & Sons, Ltd. Self-archiving of the author-manuscript version is not yet supported by this publisher. Please refer to the journal link for access to the definitive, published version or contact the author for more information.
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Inorganic Chemistry
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