Temperature dependence of the proton nuclear magnetic resonance spectra of some diamagnetic N,N-dialkyldithiocarbamate complexes of transition metals

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GOLDING, RM
HEALY, PC
NEWMAN, PWG
SINN, E
WHITE, AH
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1972
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Abstract

Unusual structure and temperature dependent behavior of the proton nmr spectrum in a number of diamagnetic N,Ndialkyldithiocarbamate complexes of di- and trivalent transition metal ions, [M(CSLNRZ)~n ]=, 2, 3 may be accounted for by a total line-shape analysis in terms of an appropriate and general two-proton exchange model using a density matrix formalism. This has been done in detail for a limited range of basic, well-defined, simple, and representative members of the above series, using the diethyl-, di-n-propyl-, diisopropyl-, diisobutyl-, and dibenzyldithiocarbamates of nickel(I1) and cobalt(II1) Where possible a tentative physical interpretation of the model is given.

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Inorganic Chemistry

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11

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10

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© 1972 American Chemical Society. Self-archiving of the author-manuscript version is not yet supported by this publisher. The contents of this journal can be freely accessed online via the ACS web page Use hypertext link above to access the ACS website.

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Inorganic chemistry

Physical chemistry

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