Supervisor-subordinate similarity affects a number of workplace outcomes, but the effect of similarity in work-family values is not well understood. Our sample consisted of 209 participants (121 female and 88 male) from a range of occupations. A structural model was tested in which subordinate perceptions of supervisor work-family value similarity predicted increased supervisor support and reduced family conflict, with an indirect effect through these variables to job satisfaction. Higher work-family conflict and lower job satisfaction had significant paths to emotional exhaustion, as a key indicator of burnout. Structural equation modeling indicated a good fit to the model for both men and women. Similarity of work-family values influenced emotional exhaustion through its impact on work-family conflict and job satisfaction.