o-Aminothiophenol in Reactions with Carbonyl Compounds and Isocyanides: A Word of Caution

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Tsirulnikov, Sergey
Dmitriev, Dmitry
Krasavin, Mikhail
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2010
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Abstract

The reaction of o-aminothiophenol with carbonyl compounds and t-BuNC was revisited and shown to provide 1-[1,3-benzothiazol-3(2H)-yl]methanimines (not described hitherto) and not the earlier reported 4H-benzo[1,4]thiazine. To isolate the latter using this reaction a due amount of caution and structure scrutiny is warranted. The basis for assignment of the products to both structural classes is provided.

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13

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© 2010 Georg Thieme Verlag. This is the author-manuscript version of the paper. Reproduced in accordance with the copyright policy of the publisher. The definitive version is available at www.thieme-connect.com.

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Organic Chemical Synthesis

Medicinal and Biomolecular Chemistry

Organic Chemistry

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