4-(Prop-2-yn-1-yloxy)benzene-1,2-dicarbonitrile

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Chin, Yee Jan
Tan, Ai Ling
Wimmer, Franz L.
Mirza, Aminul Huq
Young, David
Ng, Seik Weng
Tiekink, Edward R. T.
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2012
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Abstract

In the title compound, C11H6N2O, the complete mol­ecule is generated by the application of crystallographic twofold symmetry (the mol­ecule is disordered about this axis). The prop-2-yn-1-yl residue is slightly twisted out of the plane of the benzene ring [C-O-C-C torsion angle = 173.1 (3)°] and is orientated away from the nitrile substituents. In the crystal, supra­molecular chains along the a axis, arising from C-H...N inter­actions, are connected into stacks along the c axis by [pi]-[pi] inter­actions between the benzene rings [centroid-centroid distance = 3.6978 (6) Å = length of the c axis].

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Acta Crystallographica. Section E: Structure Reports Online

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E68

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7

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© The Author(s) 2012. For information about this journal please refer to the journal’s website. All articles published in Acta Crystallographica Section E are open access and distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. See http://creativecommons.org/licenses/by/2.0/uk/legalcode

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Organic Chemical Synthesis

Chemical Sciences

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