Lewis base adducts of group 11 metal compounds. 10. The 1:1 heterobimetallic adduct of tris(pyrrolidinecarbodithioato)cobalt(III) with copper(I) bromide
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HEALY, PC
PAPASERGIO, RI
WHITE, AH
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Abstract
Reaction of copper(1) bromide with tris(pyrrolidinecarbithioato)cobalt(III) has yielded a 1 : 1 adduct that has been characterized by single-crystal X-ray structure determination. Crystals are triclinic, PT, a = 15.385 (4) A, b = 15.025 (4) A, c = 11.088 (4) A, a = 76.01 ( 2 ) O , @ = 79.67 ( 2 ) O , and 7 = 78.18 (2)'; the structure was refined by least-squares methods to a residual of 0.036 for 4369 independent observed reflections. The complex is dimeric, of the type (C~(dtc)~)CuBr~Cu(Co(dtc)w,)it,h two such units in the cell. The copper is four-coordinate by two bromine atoms and two sulfur atoms from independent carbodithioate ligands, the approach of the copper to the latter being along the pseudo-2-fold axis of the Co(dtc), species. Cu-Cu is 2.697 (2) A.
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Inorganic Chemistry
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24
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© 1985 American Chemical Society. Self-archiving of the author-manuscript version is not yet supported by this publisher. The contents of this journal can be freely accessed online via the ACS web page 12 months after publication. Use hypertext link above to access the ACS website.
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Inorganic chemistry
Physical chemistry
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