In this paper, we propose a novel method for boundary detection in close-range hyperspectral images. This method can effectively predict the boundaries of objects of similar colour but different materials. To effectively extract the material information in the image, the spatial distribution of the spectral responses of different materials or endmembers is first estimated by hyperspectral unmixing. The resulting abundance map represents the fraction of each endmember spectra at each pixel. The abundance map is used as a supportive feature such that the spectral signature and the abundance vector for each pixel are fused to form a new spectral feature vector. Then different spectral similarity measures are adopted to construct a sparse spectral-spatial affinity matrix that characterizes the similarity between the spectral feature vectors of neighbouring pixels within a local neighborhood. After that, a spectral clustering method is adopted to produce eigenimages. Finally, the boundary map is constructed from the most informative eigenimages. We created a new HSI dataset and use it to compare the proposed method with four alternative methods, one for hyperspectral image and three for RGB image. The results exhibit that our method outperforms the alternatives and can cope with several scenarios that methods based on colour images cannot handle.