A proof of Clausius' theorem for time reversible deterministic microscopic dynamics
No Thumbnail Available
File version
Author(s)
Evans, Denis J.
Williams, Stephen R.
Bernhardt, Debra
Williams, Stephen R.
Bernhardt, Debra
Griffith University Author(s)
Primary Supervisor
Other Supervisors
Editor(s)
Date
2011
Size
File type(s)
Location
License
Abstract
In 1854 Clausius proved the famous theorem that bears his name by assuming the second "law" of thermodynamics. In the present paper we give a proof that requires no such assumption. Our proof rests on the laws of mechanics, a T-mixing property, an ergodic consistency condition, and on the axiom of causality. Our result relies on some recently derived theorems, such as the Evans-Searles and the Crooks fluctuation theorems and the recently discovered relaxation and dissipation theorems.
Journal Title
Journal of Chemical Physics
Conference Title
Book Title
Edition
Volume
134
Issue
20
Thesis Type
Degree Program
School
Publisher link
Patent number
Funder(s)
Grant identifier(s)
Rights Statement
Rights Statement
Item Access Status
Note
Access the data
Related item(s)
Subject
Physical sciences
Chemical sciences
Chemical thermodynamics and energetics
Engineering