Temperature and doping dependence of the Raman scattering in 4H-SiC
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Hu, Xiaobo
Xu, Xiangang
Chen, Xiufang
Peng, Juan
Han, Jisheng
Dimitrijev, Sima
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Abstract
Raman scattering spectra of 4H-SiC with different carrier concentrations were measured from 90 K to 660 K. By using the improved empirical formula and the energy-time uncertainty relation, temperature and doping dependence of Raman shift and phonon lifetimes were studied. For the folded transverse acoustic (FTA) and longitudinal optical (FLO) mode with E2 symmetry, the doping process induced the decrease of the c- and a-axis lattice constants which led to the changes of the vibrational frequencies and was the dominant contribution to the difference of the first- and second-order temperature coefficients. And the anharmonic decay of the phonons was established as the dominant mechanism affecting the phonon lifetimes of E2(FTO) mode at all temperatures. It is observed the phonon-carrier interaction directly determines the Raman shift and lifetimes of the folded longitudinal optical (FLO) mode with A1 symmetry.
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Optical Materials Express
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6
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9
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© 2016 Optical Society of America. Users may use, reuse, and build upon the article, or use the article for text or data mining, so long as such uses are for non-commercial purposes and appropriate attribution is maintained. All other rights are reserved.
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Atomic, molecular and optical physics
Atomic, molecular and optical physics not elsewhere classified
Nanotechnology