Highly electrocatalytic hybrid silver nanowire-graphene counter electrode for Co3+/2+ redox mediator based dye-sensitized solar cells

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Al-Mamun, Mohammad
Kim, Jae-Yup
Lee, Kyung-Jae
Ko, Young-Hui
Lee, Ji-Hoon
In, In-Sik
Lee, Ju-Won
Sung, Yung-Eun
Kim, Sung-Ryong
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2013
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Abstract

Solution processed hybrid silver nanowire (AgNW)-graphene nanoplatelets (GNP) films were prepared and the electrocatalytic activity for the cobalt redox electrolyte in dye-sensitized solar cells (DSSCs) was examined. Cyclic voltammograms and Tafel polarization measurements confirmed the superior electrocatalytic activity of AgNW-GNP electrode than that of standard Pt counter electrode (CE). Electrochemical impedance spectroscopic (EIS) study also revealed the lower charge transfer resistance (Rct) of AgNW-GNP compared to Pt based CE. However, the resistance of the electrolyte diffusion was higher for the AgNW-GNP based CE resulted from the porous structure of the hybrid CE. The photoconversion efficiencies of the DSSC prepared with AgNW-GNP based CE was found to be 2.44%, which was comparable to that of Pt based DSSC, 2.55%. This study proposed an alternative low-cost cathode material for the cobalt redox mediator based DSSCs.

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Synthetic Metals

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177

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© 2013 Elsevier. Licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (http://creativecommons.org/licenses/by-nc-nd/4.0/), which permits unrestricted, non-commercial use, distribution and reproduction in any medium, providing that the work is properly cited.

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Condensed matter physics

Materials engineering

Materials engineering not elsewhere classified

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