Highly electrocatalytic hybrid silver nanowire-graphene counter electrode for Co3+/2+ redox mediator based dye-sensitized solar cells
File version
Accepted Manuscript (AM)
Author(s)
Kim, Jae-Yup
Lee, Kyung-Jae
Ko, Young-Hui
Lee, Ji-Hoon
In, In-Sik
Lee, Ju-Won
Sung, Yung-Eun
Kim, Sung-Ryong
Griffith University Author(s)
Primary Supervisor
Other Supervisors
Editor(s)
Date
Size
File type(s)
Location
Abstract
Solution processed hybrid silver nanowire (AgNW)-graphene nanoplatelets (GNP) films were prepared and the electrocatalytic activity for the cobalt redox electrolyte in dye-sensitized solar cells (DSSCs) was examined. Cyclic voltammograms and Tafel polarization measurements confirmed the superior electrocatalytic activity of AgNW-GNP electrode than that of standard Pt counter electrode (CE). Electrochemical impedance spectroscopic (EIS) study also revealed the lower charge transfer resistance (Rct) of AgNW-GNP compared to Pt based CE. However, the resistance of the electrolyte diffusion was higher for the AgNW-GNP based CE resulted from the porous structure of the hybrid CE. The photoconversion efficiencies of the DSSC prepared with AgNW-GNP based CE was found to be 2.44%, which was comparable to that of Pt based DSSC, 2.55%. This study proposed an alternative low-cost cathode material for the cobalt redox mediator based DSSCs.
Journal Title
Synthetic Metals
Conference Title
Book Title
Edition
Volume
177
Issue
Thesis Type
Degree Program
School
Publisher link
Patent number
Funder(s)
Grant identifier(s)
Rights Statement
Rights Statement
© 2013 Elsevier. Licensed under the Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International (http://creativecommons.org/licenses/by-nc-nd/4.0/), which permits unrestricted, non-commercial use, distribution and reproduction in any medium, providing that the work is properly cited.
Item Access Status
Note
Access the data
Related item(s)
Subject
Condensed matter physics
Materials engineering
Materials engineering not elsewhere classified