Cyclic products of the Ugi reaction of aldehydo and keto carboxylic acids: chemoselective modification
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Ilyin, Alexei
Tkachenko, Sergey
Ivachtchenko, Alexandre
Kravchenko, Dmitry
Krasavin, Mikhail
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Abstract
A method for the chemoselective reduction of Ugi-type lactam amides at the lactam carbonyl functionality with borane complexes has been developed. The novel reduction products can be further manipulated synthetically to yield various novel N- and C-terminally active unnatural amino acid building blocks.
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Tetrahedron Letters
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52
Issue
15
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© 2011 Elsevier. This is the author-manuscript version of this paper. Reproduced in accordance with the copyright policy of the publisher. Please refer to the journal's website for access to the definitive, published version.
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Subject
Organic Chemical Synthesis
Medicinal and Biomolecular Chemistry
Organic Chemistry