Sub-structure syntheses and relative stereochemistry in the bistramide (bistratene) series of marine metabolites

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Gallagher, PO
McErlean, CSP
Jacobs, MF
Watters, DJ
Kitching, W
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2002
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Abstract

The (6R*,9S*,11S*) and (22S*,23R*,27R*,31R*) stereochemistry, respectively, of the tetrahydropyranyl and spiroacetal moieties in bistramide A (1) have been established by stereoselective syntheses and high field NMR comparisons. Routes to the ?-amino acid moiety are outlined.

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Tetrahedron Letters

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43

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© 2002 Elsevier : Reproduced in accordance with the copyright policy of the publisher : This journal is available online - use hypertext links.

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Medicinal and biomolecular chemistry

Organic chemistry

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