CoOx@Co Nanoparticle‐based Catalyst for Efficient Selective Transfer Hydrogenation of α,β‐Unsaturated Aldehydes
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Han, Miaomiao
Chen, Chun
Lin, Yue
Wang, Guozhong
Zhang, Haimin
Zhao, Huijun
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Abstract
Currently, developing simple and effective catalysts for selective hydrogenation of α,β‐unsaturated aldehydes to unsaturated alcohols is challenging. Herein, an efficient CoOx‐shell/Co‐core structured nanoparticle catalyst is synthesized by a facile ultrasonic‐assisted carbothermal reduction method. The resultant catalyst exhibits outstanding catalytic performance toward the selective transfer hydrogenation of a wide spectrum of α,β‐unsaturated aldehydes into corresponding unsaturated alcohols with over 90 % selectivity. This is the simplest nonprecious metal catalyst to be reported for the selective hydrogenation of unsaturated aldehydes.
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This publication has been entered into Griffith Research Online as an Advanced Online Version.
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Inorganic chemistry
Physical chemistry
Chemical engineering
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Gong, W; Han, M; Chen, C; Lin, Y; Wang, G; Zhang, H; Zhao, H, CoOx@Co Nanoparticle-based Catalyst for Efficient Selective Transfer Hydrogenation of α,β-Unsaturated Aldehydes, ChemCatChem, 2019