ent-Labdane Diterpenes from the Stems of Mallotus japonicus
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Tang, Chunping
Quinn, Ronald J
Feng, Yunjiang
Ke, Chang-Qiang
Yao, Sheng
Ye, Yang
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Abstract
Eight new ent-labdane diterpenoids, mallonicusins A-H (1-8), were isolated from the stems of Mallotus japonicus. Their structures, including the absolute configurations, were determined by extensive analyses of spectroscopic data and the ECD spectra of the Pr(FOD)3 complex of substrates in CCl4. The absolute configuration of compound 1 was confirmed by single-crystal X-ray crystallography using Cu Ka radiation.
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Journal of Natural Products
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76
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9
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Chemical sciences
Medicinal and biomolecular chemistry not elsewhere classified
Biological sciences
Biomedical and clinical sciences
Traditional, complementary and integrative medicine