Continuous-flow synthesis of mesoporous SBA-15

Loading...
Thumbnail Image
File version

Accepted Manuscript (AM)

Author(s)
Parlett, Christopher MA
Arandiyan, Hamidreza
Durndell, Lee J
Isaacs, Mark A
Lopez, Antonio Torres
Wong, Roong J
Wilson, Karen
Lee, Adam F
Griffith University Author(s)
Primary Supervisor
Other Supervisors
Editor(s)
Date
2022
Size
File type(s)
Location
Abstract

Ordered mesoporous silicas are widely used in separation science and catalysis, however, their slow batch synthesis is a barrier to scale-up and new applications. SBA-15 is one of the most extensively studied and commercially available mesoporous silicas, whose textural properties can be readily tuned through judicious choice of synthesis conditions. Here we demonstrate the continuous flow synthesis of SBA-15 in high yield at 80 °C using a simple tube reactor without any mixing device. The resulting SBA-15 exhibits excellent textural properties, with a BET surface area of 566 m2 g−1 and ordered 5.1 nm mesopore channels in a p6mm arrangement, akin to those from conventional batch synthesis, but with far higher productivity than previously reported in batch or flow (5.3 g L−1 h−1 versus 0.4 and 0.6 g L−1 h−1 respectively).

Journal Title

Microporous and Mesoporous Materials

Conference Title
Book Title
Edition
Volume

329

Issue
Thesis Type
Degree Program
School
Publisher link
Patent number
Funder(s)

ARC

Grant identifier(s)

DP200100313

Rights Statement
Rights Statement

© 2021. This manuscript version is made available under the CC-BY-NC-ND 4.0 license https://creativecommons.org/licenses/by-nc-nd/4.0/

Item Access Status
Note
Access the data
Related item(s)
Subject

Chemical sciences

Engineering

Persistent link to this record
Citation

Parlett, CMA; Arandiyan, H; Durndell, LJ; Isaacs, MA; Lopez, AT; Wong, RJ; Wilson, K; Lee, AF, Continuous-flow synthesis of mesoporous SBA-15, Microporous and Mesoporous Materials, 2022, 329, pp. 111535

Collections